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Ultrafast-laser-treated poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) electrodes with enhanced conductivity and transparency for semitransparent perovskite solar cells

《化学科学与工程前沿（英文）》 2023年 第17卷 第2期   页码 206-216 doi: 10.1007/s11705-022-2203-x

摘要： Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is an important organic electrode for solution-processed low-cost electronic devices. However, it requires doping and post-solvent treatment to improve its conductivity, and the chemicals used for such treatments may affect the device fabrication process. In this study, we developed a novel route for exploiting ultrafast lasers (femtosecond and picosecond laser) to simultaneously enhance the conductivity and transparency of PEDOT:PSS films and fabricate patterned solution-processed electrodes for electronic devices. The conductivity of the PEDOT:PSS film was improved by three orders of magnitude (from 3.1 to 1024 S·cm–1), and high transparency of up to 88.5% (average visible transmittance, AVT) was achieved. Raman and depth-profiling X-ray photoelectron spectroscopy revealed that the oxidation level of PEDOT was enhanced, thereby increasing the carrier concentration. The surface PSS content also decreased, which is beneficial to the carrier mobility, resulting in significantly enhanced electrical conductivity. Further, we fabricated semitransparent perovskite solar cells using the as-made PEDOT:PSS as the transparent top electrodes, and a power conversion efficiency of 7.39% was achieved with 22.63% AVT. Thus, the proposed route for synthesizing conductive and transparent electrodes is promising for vacuum and doping-free electronics.

关键词： PEDOT:PSS     ultrafast laser     transparent electrode     ST-PSCs     patterning    

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Preparation of transparent BaSO

Le Fang, Qian Sun, Yong-Hong Duan, Jing Zhai, Dan Wang, Jie-Xin Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 902-912 doi: 10.1007/s11705-020-1985-y

摘要： BaSO nanoparticles as important functional materials have attracted considerable research interests, due to their X-rays barrier and absorption properties. However, most of BaSO nanoparticles prepared by traditional technology are nanopowders with broad size distribution and poor dispersibility, which may greatly limit their applications. To the best of our knowledge, the synthesis of transparent BaSO nanodispersions was rarely reported. Here, we firstly present a novel and efficient method to prepare transparent and stable BaSO nanodispersions with a relatively small particle size around 10 to 17 nm using a precipitation method in a rotating packed bed (RPB), followed by a modification treatment using stearic acid. Compared with the BaSO prepared in a traditional stirred tank, the product prepared using an RPB has much smaller particle size and narrower size distribution. More importantly, by using RPB, the reaction time can be significantly decreased from 20 min to 18 s. Furthermore, the transparent BaSO -polyvinyl butyral nanocomposite films with good X-ray shielding performance can be easily fabricated. We believe that the stable BaSO nanodispersions may have a wide range of applications for transparent composite materials and coatings with X-ray shielding performance for future research.

关键词： BaSO4 nanoparticles     rotating packed bed     transparent nanodispersions     BaSO4-PVB films     X-ray shielding    

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Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1427-1443 doi: 10.1007/s11705-021-2108-0

摘要： The dye industry produces a large amount of hazardous wastewater every day worldwide, which brings potential threaten to the global environment. As an excellent method for removal of water chroma and chemical oxygen demand, electrocatalytic methods are currently widely used in the treatment of dye wastewater. The selection and preparation of electrode materials and electrocatalysts play an important role on the electrocatalytic treatment. The aim of this paper is to introduce the most excellent high-efficiency electrode materials and electrocatalysts in the field of dye wastewater treatment. Many electrode materials such as metal electrode materials, boron-doped diamond anode materials and three-dimensional electrode are introduced in detail. Besides, the mechanism of electrocatalytic oxidation is summarized. The composite treatment of active electrode and electrocatalyst are extensively examined. Finally, the progress of photo-assisted electrocatalytic methods of dye wastewater and the catalysts are described.

关键词： electrocatalytic oxidation     electrode     electrocatalysis     dye wastewater    

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Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

《机械工程前沿（英文）》 2010年 第5卷 第4期   页码 412-417 doi: 10.1007/s11465-010-0114-x

摘要： The behaviors of electrode displacement and force during spot welding under various conditions, such as different weld currents, electrode forces, and welding times, were studied. Tests were conducted on a 170?kVA MFDC spot welder. Data were collected via a multichannel high-speed data acquisition system and were analyzed with MATLAB. Behaviors of 5182 aluminum and mild steel in spot welding were compared. Results show that nugget expansion rate does not reach zero for aluminium as it does for mild steel as nugget grew to a certain size. A linear relationship is found between the nugget size and maximum expansion that facilitates online weld quality evaluation. An electrode force peak is observed and believed relevant to the sufficient nugget size.

关键词： aluminum     electrode displacement     electrode force     nugget size     data acquisition    

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Model test and discrete element method simulation of shield tunneling face stability in transparent clay

Huayang LEI, Yajie ZHANG, Yao HU, Yingnan LIU

《结构与土木工程前沿（英文）》 2021年 第15卷 第1期   页码 147-166 doi: 10.1007/s11709-020-0704-6

摘要： The stability of the shield tunneling face is an extremely important factor affecting the safety of tunnel construction. In this study, a transparent clay with properties similar to those of Tianjin clay is prepared and a new transparent clay model test apparatus is developed to overcome the “black box” problem in the traditional model test. The stability of the shield tunneling face (failure mode, influence range, support force, and surface settlement) is investigated in transparent clay under active failure. A series of transparent clay model tests is performed to investigate the active failure mode, influence range, and support force of the shield tunneling face under different burial depth conditions, whereas particle flow code three-dimensional numerical simulations are conducted to verify the failure mode of the shield tunneling face and surface settlement along the transverse section under different burial depth conditions. The results show that the engineering characteristics of transparent clay are similar to those of soft clay in Binhai, Tianjin and satisfy visibility requirements. Two types of failure modes are obtained: the overall failure mode (cover/diameter: / ≤1.0) and local failure mode ( / ≥2.0). The influence range of the transverse section is wider than that of the longitudinal section when / ≥2.0. Additionally, the normalized thresholds of the relative displacement and support force ratio are 3%–6% and 0.2–0.4, respectively. Owing to the cushioning effect of the clay layer, the surface settlement is significantly reduced as the tunnel burial depth increases.

关键词： shield tunneling face     stability     transparent clay     model test     numerical simulation    

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A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber

《环境科学与工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1800-y

摘要：

● A spindle-shaped influent chamber was designed and equipped in FCDI system.

关键词： Spindle-shaped chamber     Desalination performance     Flow electrode capacitive deionization    

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A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

《能源前沿（英文）》 2019年 第13卷 第2期   页码 325-338 doi: 10.1007/s11708-019-0618-y

摘要： Polymer electrolyte membrane (PEM) fuel cell is the most promising among the various types of fuel cells. Though it has found its applications in numerous fields, the cost and durability are key barriers impeding the commercialization of PEM fuel cell stack. The crucial and expensive component involved in it is the gas diffusion electrode (GDE) and its degradation, which limits the performance and life of the fuel cell stack. A critical analysis and comprehensive understanding of the structural and functional properties of various materials involved in the GDE can help us to address the related durability and cost issues. This paper reviews the key GDE components, and in specific, the root causes influencing the durability. It also envisages the role of novel materials and provides a critical recommendation to improve the GDE durability.

关键词： PEM fuel cell     gas diffusion electrode(GDE)     gas diffusion layer(GDL)     membrane electrode assembly     durability     fuel cell catalyst    

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ImgFS: a transparent cryptography for stored images using a filesystem in userspace

Osama A. KHASHAN,Abdullah M. ZIN,Elankovan A. SUNDARARAJAN

《信息与电子工程前沿（英文）》 2015年 第16卷 第1期   页码 28-42 doi: 10.1631/FITEE.1400133

摘要： Real-time encryption and decryption of digital images stored on end-user devices is a challenging task due to the inherent features of the images. Traditional software encryption applications generally suffered from the expense of user convenience, performance efficiency, and the level of security provided. To overcome these limitations, the concept of transparent encryption has been proposed. This type of encryption mechanism can be implemented most efficiently with kernel file systems. However, this approach has some disadvantages since developing a new file system and attaching it in the kernel level requires a deep understanding of the kernel internal data structure. A filesystem in userspace (FUSE) can be used to bridge the gap. Nevertheless, current implementations of cryptographic FUSE-based file systems suffered from several weaknesses that make them less than ideal for deployment. This paper describes the design and implementation of ImgFS, a fully transparent cryptographic file system that resides on user space. ImgFS can provide a sophisticated way to access, manage, and monitor all encryption and key management operations for image files stored on the local disk without any interaction from the user. The development of ImgFS has managed to solve weaknesses that have been identified on cryptographic FUSE-based implementations. Experiments were carried out to measure the performance of ImgFS over image files’ read and write against the cryptographic service, and the results indicated that while ImgFS has managed to provide higher level of security and transparency, its performance was competitive with other established cryptographic FUSE-based schemes of high performance.

关键词： Storage image security     Cryptographic file system     Filesystem in userspace (FUSE)     Transparent encryption    

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Utilizing transparent and conductive SnO

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen, Junfeng Niu

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1251-z

摘要： Abstract • A novel Z-scheme Si-SnO2-TiOx with SnO2 as electron mediator is first constructed. • Transparent and conductive SnO2 can pass light through and promote charge transport. • VO from SnO2 and TiOx improve photoelectrochemical performances. • Efficient photocatalytic degradations originate from the Z scheme construction. Z-scheme photocatalysts, with strong redox ability, have a great potential for pollutants degradation. However, it is challenging to construct efficient Z-scheme photocatalysts because of their poor interfacial charge separation. Herein, by employing transparent and conductive SnO2 as electron mediator to pass light through and promote interfacial charge transportation, a novel Z-scheme photocatalyst Si-SnO2-TiOx (1

关键词： Z-scheme photocatalyst     Tin oxide     Electron mediator     Organic pollutant    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1345-7

摘要： Abstract • Electrode fouling is characterized by non-destructive characterization. • Electrode fouling is highly dependent on electrochemical process. • Active chlorine can prevent the formation of polymeric fouling film. Electrode fouling is a problem that commonly occurs during electro-oxidation water purification. This study focused on identifying the fouling behavior of Pt electrode associated with the formation of polymeric layer during electro-oxidation of phenol. The in situ electrochemical measurements and non-destructive observation of the electrode morphology were reported. The results demonstrated that the electrode fouling was highly dependent on thermodynamic process of electrode that was controlled by anode potential. At anode potential lower than 1.0 V vs SHE, the direct electro-oxidation caused the electrode fouling by the formation of polymeric film. The fouling layer decreased the electrochemically active surface area from 8.38 cm2 to 1.57 cm2, indicated by the formation of polymeric film with thickness of 2.3 mm, increase in mass growing at a rate of 3.26 μg/cm2/min. The degree to which the anode was fouled was independent of anion in the electrolyte. In comparison, at anode potential higher than 2.7 V vs SHE, the anions (e.g., chloride) could exert a major influence to the behavior of electrode fouling. The presence of chloride was shown to mitigate the fouling of electrode significantly through preventing the formation of polymeric film by active chlorine (e.g., Cl• and Cl2) produced from anodic oxidation of chloride. Since chloride is the most abundant anionic species existing in both natural and engineered water system, this study not only offers a deep insight into the mechanism of electrode fouling, but also suggests strategies for anti-fouling in the presence of chloride in electro-oxidation process.

关键词： Electro-oxidation     Electrode fouling     Polymeric film     Chloride ions    

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从资源共享到服务共享：透明计算的机遇与挑战

张尧学,周悦芝

《中国工程科学》 2009年 第11卷 第8期   页码 10-17

摘要：

随着计算机和网络技术以及应用的不断快速发展，计算模式从最初的以主机计算为主，发展到以桌面(PC)计算为主，再发展到现在的以网络计算为主，乃至普适计算。然而，迄今为止的计算模式还是遵循以单机或单机联合为基础的单机思维模式，因此，目前的计算模式还是一种以“资源共享”为主要特征的计算。在网络和普适计算的新时代，用户关心的主要是服务和服务共享，计算机也将从以“资源共享”为特征的计算过渡到以“服务共享”为特征的计算。笔者提出一种适应于“服务共享”的计算模式——透明计算，并对其概念、体系结构及相关关键技术进行介绍。此外，还对透明计算的未来发展及影响进行展望。

关键词： 普适计算     资源共享     服务共享     透明计算    

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纤维膜在机械压力下由不透明到透明的转变 Article

王超, 赵景, 刘柳, 张鹏, 王先锋, 俞建勇, 丁彬

《工程（英文）》 2022年 第19卷 第12期   页码 84-92 doi: 10.1016/j.eng.2021.02.018

摘要：

智能可穿戴设备、电子皮肤、空气过滤和组织工程等领域，对透明薄膜材料或基材的需求很大。传统透明材料，如玻璃、塑料等，由于缺乏相互连通的孔道、不理想的孔隙率和柔性，不能满足这些新兴领域的要求。静电纺丝纤维膜因其具有小孔径、高孔隙率和良好的柔性等优点可以弥补传统材料的不足，因此，开发透明的静电纺丝纤维膜具有重大的价值。本文报道了一种简单有效的方法，在不使用任何其他添加剂的情况下，通过机械压力，直接将静电纺丝纤维膜制备成柔性的、有孔的透明纤维膜材料。同时，首次总结了压制后聚合物的透明度性能与分子结构之间的关系。经过机械压力处理后，纤维膜仍可以保持纤维形态、微米级孔道和一定的孔隙率。以聚苯乙烯静电纺丝纤维膜为例，所制备的透明聚苯乙烯纤维膜具有优异的光学性能和机械性能。透明纤维膜可实现高透光率（≈89%，可见光波长在550 nm处）、大孔隙率（10%~30%）和强的机械拉伸强度（≈148 MPa），该拉伸强度约为初始静电纺丝纤维膜的78倍。此外，本文基于透明纤维膜，利用真空辅助抽滤银纳米线和机械压力作用，制备出透明的导电纤维膜材料。与氧化铟锡导电薄膜相比，我们所制备的透明导电纤维膜展示出良好的导电性（9 Ω·sq-1，78%的透光率）和优异的机械性能（可承受大量的弯曲应力）。

关键词： 透明     静电纺丝纤维膜     孔道结构     机械压力     导电    

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Transparent exopolymer particles (TEPs)-associated protobiofilm: A neglected contributor to biofouling

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1361-7

摘要：

• Bacteria could easily and quickly attached onto TEP to form protobiofilms.

关键词： Transparent exopolymer particles (TEPs)     TEP-protobiofilm     Bacteria attachment     Biofouling of membrane    

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Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1697-x

摘要：

● Titanium-based flow-through electrode achieved high Cr(VI) reduction efficiency.

关键词： Flow-through electrode     Hexavalent chromium     Heavy metals     Neural network     Artificial intelligence    

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标题 作者 时间 类型 操作

Ultrafast-laser-treated poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) electrodes with enhanced conductivity and transparency for semitransparent perovskite solar cells

期刊论文

Preparation of transparent BaSO

Le Fang, Qian Sun, Yong-Hong Duan, Jing Zhai, Dan Wang, Jie-Xin Wang

期刊论文

Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

期刊论文

Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

期刊论文

Model test and discrete element method simulation of shield tunneling face stability in transparent clay

Huayang LEI, Yajie ZHANG, Yao HU, Yingnan LIU

期刊论文

A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber

期刊论文

A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

期刊论文

ImgFS: a transparent cryptography for stored images using a filesystem in userspace

Osama A. KHASHAN,Abdullah M. ZIN,Elankovan A. SUNDARARAJAN

期刊论文

Utilizing transparent and conductive SnO

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen, Junfeng Niu

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

期刊论文

从资源共享到服务共享：透明计算的机遇与挑战

张尧学,周悦芝

期刊论文

纤维膜在机械压力下由不透明到透明的转变

王超, 赵景, 刘柳, 张鹏, 王先锋, 俞建勇, 丁彬

期刊论文

Transparent exopolymer particles (TEPs)-associated protobiofilm: A neglected contributor to biofouling

期刊论文

Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

期刊论文